Copper removal from acid mine drainage-polluted water using glutaraldehyde-polyethyleneimine modified diatomaceous earth particles
نویسندگان
چکیده
Mine waters and tailings generated from mining and mineral processing activities often have detrimental impact on the local environment. One example is acid mine drainage, in which sulphides in the mining waste react with water and oxygen to produce an acidic environment that subsequently dissolves host rock minerals from the waste containing toxic metals and trace elements. Copper is one such metal of significance, as it is mined at large volumes in sulphide containing ores. It has strong biocidal activity that greatly affects ecosystems. We have previously reported that glutaraldehyde (GA)-crosslinked polyethyleneimine (PEI) has strong affinity and selectivity for copper and that diatomaceous earth (DE) particles can be modified with the material to form a copper-extraction resin. In this study, the copper uptake of GA-PEI-DE particles was investigated from synthetic and real acid mine drainage samples under different pHs and their copper removal performance was compared with that of selected commercial resins. The results revealed that copper could effectively and preferentially bind to the material at pH 4, and that the copper could be completely eluted by lowering of the pH. In addition, effective copper uptake and elution was demonstrated using real legacy acid mine drainage water from Mount Lyell in Tasmania.
منابع مشابه
Toxic metal removal from aqueous solution by advanced Carbon allotropes: a case study from the Sungun Copper Mine
The sorption efficiencies of graphene oxide (GO) and functionalized multi-walled carbon nanotubes (f-MWCNTs) were investigated and elucidated to study their potential in treating acid mine drainage (AMD) containing Cu2+, Mn2+, Zn2+, Pb2+, Fe3+ and Cd2+ metal ions. Several layered GO nanosheets and f-MWCNTs were formed via the modified Hummers’ method and the acid treatment of the MWCNTs, respec...
متن کاملTowards "Precision Mining" of wastewater: Selective recovery of Cu from acid mine drainage onto diatomite supported nanoscale zerovalent iron particles.
This paper introduces the concept of 'Precision Mining' of metals which can be defined as a process for the selective in situ uptake of a metal from a material or media, with subsequent retrieval and recovery of the target metal. In order to demonstrate this concept nanoscale zerovalent iron (nZVI) was loaded onto diatomaceous earth (DE) and tested for the selective uptake of Cu from acid mine ...
متن کاملPrediction of Acid Mine Drainage Generation Potential of A Copper Mine Tailings Using Gene Expression Programming-A Case Study
This work presents a quantitative predicting likely acid mine drainage (AMD) generation process throughout tailing particles resulting from the Sarcheshmeh copper mine in the south of Iran. Indeed, four predictive relationships for the remaining pyrite fraction, remaining chalcopyrite fraction, sulfate concentration, and pH have been suggested by applying the gene expression programming (GEP) a...
متن کاملBio-Remediation of Acid Mine Drainage in the Sarcheshmeh Porphyry Copper Mine by Fungi: Batch and Fixed Bed Process
Acid mine drainage (AMD) containing high concentrations of iron and sulphate, low pH and variableconcentrations of heavy metals leads to many environmental problems. The concentrations of Cu and Mnare high in the AMD of the Sarcheshmeh porphyry copper mine, Kerman province, south of Iran. In thisstudy, the bio-remediation of Cu and Mn ions from acid mine drainage was investigated using two nati...
متن کاملUse of modified diatomaceous earth for removal and recovery of viruses in water.
Diatomaceous earth was modified by in situ precipitation of metallic hydroxides. Modification decreased the negative charge on the diatomaceous earth and increased its ability to adsorb viruses in water. Electrostatic interactions were more important than hydrophobic interactions in virus adsorption to modified diatomaceous earth. Filters containing diatomaceous earth modified by in situ precip...
متن کامل